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Synthesis 2016; 48(23): 4181-4188
DOI: 10.1055/s-0035-1562790
DOI: 10.1055/s-0035-1562790
paper
Application of 5-Ethoxymethylfurfural (EMF) for the Production of Cyclopentenones
Authors
Further Information
Publication History
Received: 19 April 2016
Accepted after revision: 06 July 2016
Publication Date:
17 August 2016 (online)
Abstract
We describe a method for the conversion of 5-ethoxymethylfurfural (EMF) into substituted cyclopentenones in a stereoselective manner through application of the Piancatelli rearrangement. The strategy allows the utilization of biomass-derived C6-carbohydrates for the production of cyclopentenones, making them a possible platform chemical for the sustainable chemical industry.
Key words
cyclopentenone - 5-ethoxymethylfurfural - 5-hydroxymethylfurfural - Piancatelli rearrangement - biomass valorizationSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1562790.
- Supporting Information (PDF)
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